Heat Capacity/Specific Heat Capacity and molar specific heat capacity


s


Heat Capacity

Heat capacity (C) of a substance is “the quantity of heat needed to raise the temperature of a substance by one degree Celsius (or one Kelvin).” The heat capacity differ from substance to substance. The amount of substance is directly proportional to the heat capacity. That means by doubling the mass of substance, heat capacity can be doubled.

 C = QΔ/Δt

Where the QΔ is the amount of heat required with the change or temperature .

 Unit:  The S.I unit of heat capacity is JK-1.

 


Specific Heat Capacity

It can be defined as “the quantity of heat required to raise the temperature of one gram of a substance by one degree Celsius (or one Kelvin) at a constant pressure.”

 Specific heat or specific heat capacity (s) is the heat capacity, which is independent of the amount of substances

            Thus if the ΔQ is the amount of heat added to raise the temperature of ‘m’ kg of a substance through ΔT, then

ΔQ  µ ΔT_________(a)

ΔQ  µ m_________(b)

Combine both (a) and (b)

ΔQ  µ m ΔT

   ΔQ = c m ΔT

     c = ΔQ/m ΔT

Where ‘c’ is the proportionality constant known as specific capacity of the substances.

Unit

The unit of specific heat is Jg-1oC-1.


Molar Specific Heat Capacity

Heat required to raise the one degree temperature of one mole of substances.

ΔQ = c m ΔT _______(1)

n = molar mass (m) / molecular mass (M)

n = m / M

m = Mn_______(a) 

                Put equation in (a) in (1)

ΔQ = c nMΔT

Where “Product of Molecular mass (M) and  specific heat capacity “c” is equal to Molar specific heat capacity ‘C”.

C = Mc

            Then the equation ‘2’ will be

                                                                            ΔQ = nC

                                                                        C = ΔQ / n ΔT 


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